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If You have older wine version than 1.7 - uninstall it.
Add ppa repository for latest wine version
Run Your favourite package manager to install Wine 1.7 ie. SYNAPTIC
Check Wine 1.7 or newer and winetricks.
After instalation check wine version
run "winetricks" from console and install packages
Run Lightroom 4 or 5 installation.
Now the files are unpacked
When done, run setup32.exe. 64bit version not working. If You get message about "...that Your computer is running Windows Vista or later", You need change wine configuration from Windows XP to Windows Vista or later.
After instalation run LR from desktop icon. If everything went well, Ligtroom will start.